Is it possible to replicate the digital->film transition with tone mapping? (I assume the answer is yes, but what is the actual mapping?)
The "best" right now, in my opinion, is AgX, which at this point has various "flavours" that operate slightly differently. You can find a nice comparison of OCIO configs here: https://liamcollod.xyz/picture-lab-lxm/CAlc-D8T-dragon
I went down the tonemapping rabbit hole for a hobby game engine project a while ago and was surprised at how complex the state-of-the-art is.