I'm thinking of building a small PCB for ballooning too.
But I most likely will shift the design decisions a bit:
- 2.4GHz LoRa for high-rate telemetry as reciving can recycle Wifi-Antenna gear. The Semtech SX128x chips are easy to handle.
- Low rate telemetry on 433MHz with a SX12xx or SX17xx.
In terms of chips most likely something around the STM32U series.
The company ePeas has very interesting energy harvesters. Not super cheap - but still affordable. They have special profiles for supercaps which are very resistant against freezing.