Idea of gravity-assist acceleration, mechanically is just rotation of pair tightly tied bodies (and cut tie in right moment, so one body got acceleration and other got deceleration), but as it is impractical to tie for example to Moon with rope, used gravity force.
What also interesting, gravity-assist could use not only orbital speed of large body, but also got some acceleration from rotation of large body, as for gravitation, large planet is not just one material point, but system of few smaller (sub)bodies, and closer (sub)bodies give more acceleration than others.
The voyager craft, which not only had very good acceleration early on (the best we could do, really), combined with exceptional gravity slingshots and a lot of time - and are by all accounts some of the fastest man made objects ever - are going 15.4 km/s and 17 km/s relative to the sun.
3I/ATLAS is going so much faster than these objects they might as well be stationary.
Even ignoring the limited amount of time we have to intercept, catching up to 3I/ATLAS would be incredibly difficult to do. Perhaps impossible with our current technology*. Like catching up to a semi-truck going full speed on a highway with a bicycle. After it’s already passed us and is a couple miles down the road.
*barring theoretical (and kind of insane and dangerous) tech like Orion drives.