I had a debit card with some hundreds of EUR already charged, but I ended up using it with an NFC enabled smartphone.
No issues at all, even going in far places outside Barcelona. Everyone very receptive in BCN.
I looked at ATM terminals and they seemed full of rules and complications. I tried to get some cash just to collect the notes as a souvenir, but I gave up.
Again, everyone accepted my NFC enabled smartphone, I tested my debit NFC card and my local bank CC NFC card as well
So I think ATMs present a lot of friction for sure.