Check the throughput graphs from this blog post from 2020 (for improvements I made to connection scalability):
https://techcommunity.microsoft.com/blog/adforpostgresql/imp...
That's for read-mostly work. If you do write very intensely, you're going to see more contention earlier. But that's way way worse with sqlite, due to its single writer model.
EDIT: Corrected year.