Kind thought, thank you. But sometimes my life IS my startup, and thats the choice I have made.
However, my experience is that pair programming would work well in a senior/not as senior pairing, with the caveat, you need to have capacity on your projects to roll with this also technique.
regarding you choosing to sweat on your startup, fair play thats your choice, and possibly a good one if that's what you are passionate about. hopefully your end goal/mission is not just to make loads of money though!