Also, on EVs with LFP batteries the brakes do get used a bit more, because a full and/or cold pack usually can only take very limited power from regenerative braking. Depending on the implementation in the vehicle, brakes are either applied automatically to still allow for one-pedal-driving (aka. "brake blending", making the difference unnoticeable to the driver), or throttle-pedal regen is simply capped and the driver has to use the brake pedal when they notice that regen power is not sufficient.
Now I have a RWD Model 3 with an LFP pack (SR+/"base model"), and have to use the brakes much more than with the old car (that had an NMC pack and almost never limited regen). Over two years in, brakes seem good as new, hopefully they stay this way.
They fixed it by having the software to apply frictional brakes once in a while to keep the rotors clean.
I have an EV with 150k miles, and the brake pads are barely worn. They are going to outlast it.
Never had any issue with rust.