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Booting into windows (or linux). The Mac version is... incomplete.

Basically you just need to install (the "full isntaller" install the main plugin) and put your bios on bios folder and then you make an ISO of you own copy and that's it! Go to menu File Run ISO, done!

For sure, you can experiment changing video .... and so on!

Is there any specific kind of DVD drive I need to image the disc, or will the one in my MacBook Pro be able to read it?

Your Macbook should be fine, I'd probably use Disc Utility to dump the disc to an ISO if you have the space.

They're just plain DVDs, SuperDrive is fine.

Possibly a BIOS image and that might be about it. I've not tried it in a long time so I don't know how performance is at all anymore.