Besides, it introduces Granny Weatherwax, who is IMO one of his two greatest creations (the other being Vimes of course).
Edit: Oh, by the way, if you're just now working your way through them then (a) I envy you and (b) I recommend reading the Annotated Pratchett File for each book - after you finish each of course: https://www.lspace.org/books/apf/
Sadly, it’s pretty sparse or non-existent for the later books, but the TVTropes pages on them are usually very good, and cover a lot of the same ground.
I was a bit surprised by the change in tone in a way I probably wouldn't've been if I'd read chronologically.
It and Light Fantastic are both fantasy-parody travelogues, which are mostly about the protagonists moving through a sequence of largely disconnected pastiches of other fantasy works. After this the series rapidly switches to fantasy as metaphor for real-world situations, with the fantasy elements being more broad tropes rather than specifics references.
I generally recommend starting with Wyrd Sisters, since many people are familiar with Macbeth.