Incidentally, I was not aware of issues around default settings with MySQL when I switched our infrastructure to Postgres - the primary reason we switched was transactional and much more efficient DDL changes. I was at a company previously that I felt was seriously hampered from innovating due to strong resistance against schema changes by the DBAs and want to do my best to prevent a similar culture where I work.
Before I decided to switch I benchmarked schema changes between Postgres and MySQL and found Postgres to be quite impressive, see the gist of results here: https://gist.github.com/1620133. If you (or anyone else) can point out why this benchmark is false or misleading, I'm all ears.