Similarly, the Bank of England uses £100,000,000 notes internally: https://en.wikipedia.org/wiki/Bank_of_England_%C2%A3100,000,...
https://en.wikipedia.org/wiki/Banknotes_of_the_pound_sterlin...
Looks as though it's just Ulster, Scotland and the Crown Dependencies nowadays
Edit: https://en.wikipedia.org/wiki/Danske_Bank_(Northern_Ireland) Danske bank is a Northern Irish bank (I had never heard of this)
you have the same problem spending $2 bills in the US