Top employees often have an axe to grind, an ego to satisfy or a ladder to climb. This is the last thing a corporation wants or needs. When I was a manager in Corporate America, I was instructed to screen out overly ambitious or eager candidates. They are just too much trouble for what amounts to normally a 10-20% increase in performance over a regular candidate.
After all, I know Alice gets things done fast and to a high standard, she can be trusted to deliver important projects, and she's very familiar our most important systems.
All anyone else knows is her job title is "Level 17 Engineer", she's got a firm handshake, and she knows how to find a cycle in a linked list.
It'd be pretty absurd for me to let myself get outbid on salary by someone with less information.