Your engine is part of your crumple zone. You do not want your battery to be. Same reason the fuel tank is usually in the back of the vehicle.
Fuel tanks are not "in the back" for good (see: ford pinto) reasons.
A big battery in the place of the motor will turn you into a BBQ in case of collision because fire will fall directly towards the driver. Lithium batteries start burning when hit with some force, and can't be stopped once they start burning.