The minor 7 is not in the harmonic series. It’s just not there. This is not a nitpick or a quibble—the minor 7 is just a completely different interval, separate from the just intonation 7:4 interval. To my ears, it is like saying that red and yellow are the same color.
What about augmented or diminished chords? How do they fit into this theory? What about, say, the 9? Why do we put a 9 in a chord, and not a 2? Why do we like the b9? Why do we use a #11?
There’s a million little historical and cultural factors going on here. You can come up with a sort of apologia to explain why thirds make sense, but this doesn’t mean that thirds are in any sense fundamental in some physical or physiological sense.