In particular, since sums of holomorphic functions are holomorphic, the sum f(z) = z + z* of the identity function g(z) = z and conjugate function h(z) = z* would need to be holomorphic. But z + z* cancels out the imaginary part of z and therefore maps the complex plane to the real line - and it should be obvious that a map from C to R cannot possibly preserve the properties of C in any intuitive way.
Roughly speaking, the conjugate fails to be holomorphic because it maps C to its mirror image, rather than C itself, in much the same way that reflecting a circle is different from rotating it.