Depends on your definition of "there". Going from 8MB to 32MB did very little for you pre Windows95. Every piece of x86 software up to that point was maxing below 8MB because ram was insanely expensive and you needed to populate 4 modules at a time. Motherboards came standard with 4 or 8 ram slots limiting your ram choices to 1,2,4,5,8,16,17,20,32 MB with last 4 costing more than motherboard and CPU combined.
In 1992 standard desktop was still 386 + 4MB, with highend 486 + 8MB. 1MB SIMM was $30-50. 4MB $150 January 1992, dropping to $100 in December 1992, and back to $130 in December 1994.
Afaik 72 pin simms were first introduced in 1989 IBM PS/2 (55SX? proprietary variant) and later around 1993 in clones. You could run 1,2,3 or 4 simms of any size independently. In December 1994 2MB 72pin Simm was $80, 4MB $150, 8MB $300, 16MB $560. 32MB $1200, 64MB $2800.
486DX2-66 itself was ~$300, + $100 VLB motherboard meanwhile $1100 got you Pentium 90MHz with PCI motherboard. In December 1994 for the price of 486 with 32MB ram ($1600) you could have bought P90 with 16MB ($1660).