CAPTCHAs are the main reason I turned IPv6 on. No idea if it will actually help in practice, it's hard to measure.
The other Starlink hassle is the geocoding for user IPv4 addresses is wildly wrong. I'm in Grass Valley, CA near Sacramento but sites all think my IP is either in Seattle or Los Angeles, depending on the week. This makes streaming services a huge PITA, I have to jump through hoops to convince them I'm in the Sacramento TV market about once a month. IPv6 could help with this too, Starlink could give out more precisely geolocated addresses. Not sure they're doing it though, all I see are IPv4 addresses in the geocoding feed: https://geoip.starlinkisp.net/feed.csv