It is supported, but the list of broken packages is rather long... [1]
You don't need an official build, as Gentoo builds itself and also cross-builds itself for any target and any ABI. In this case, you don't even need a cross-build.
Just install Gentoo x86_64 multilib, enable x32 support in kernel, enable abi_x86_x32 USE flag for the packages you want to test and run emerge to build them. They won't even interfere with the rest of the running system. See [2].
[1] https://github.com/gentoo/gentoo/blob/master/profiles/arch/a...