Essential node in global semiconductor supply chain hit by Hurricane Helene
npr.org
npr.org
(130 points 6 months ago | 97 comments)
> These types of articles/pronouncement always tend to make a connection that is nearly never warranted. That is, the article quotes this tweet that says "The modern economy rests on a single road in Spruce Pine, North Carolina. The road runs to the two mines that is the sole supplier of the quartz required to make the crucibles needed to refine silicon wafers." But the first sentence doesn't really follow from the second.
> That is, even if all the silicon wafers are made from this quartz from NC today, it's not really because that is the only possible option, it's because that quartz is the highest quality that can be procured at a relatively low price. But if that factory and quarry went away tomorrow, I have no doubt that the worldwide semiconductor industry would quickly adjust to a different quartz supplier.
> I think it's still a very cool factoid, but the subtext that "the whole world economy 'hinges' on a teeny NC town" is false.
We'll see if they're right...
Hereus Conamic and WACKER Chemie come to mind
You know a lot more about quartz manufacturing: do you sincerely think that someone in China couldn't figure out how to make the quartz (or whatever) cheaply?
China has been trying as part of its latest (14th) five year plan but there’s a reason so much of the semiconductor supply chain is in Japan, Korea, US, and Europe: labor costs aren’t the driving force. It’s energy and capital equipment and intellectual property and decades of expertise with quality control. Everything else is secondary.
Maybe read the thread you're replying to?
https://www.mmtc.co.jp/en/products/quartz.html
"Semiconductor devices, the foundation of the semiconductor industry, are manufactured by creating a fine electronic circuit on a silicon wafer made of single-crystal silicon.
Single-crystal silicon is made from high-purity polycrystalline silicon (polysilicon) and is grown by filling a quartz crucible with the silicon before heating and melting it in the extracting machine.
A high-purity quartz crucible is the optimal container to ensure the purity of molten silicon when manufacturing single-crystal silicon."
Any other material for the crucible except quartz would introduce impurities from whatever substance it is made.
Quartz is already silicon dioxide. It could introduce only silicon atoms, which do not matter at all, or oxygen atoms, which also do not matter much.
The only alternatives to quartz would be other silicon compounds that have a melting point higher than pure silicon, e.g. silicon nitride, but all of them are more expensive than quartz.
In the past, besides the crucibles for holding melted silicon, quartz was widely used for the walls of the ovens (typically having the form of a quartz tube) where silicon wafers were heated for various operations, e.g. for diffusion, and also for the wafer carriers on which the wafers were placed while inside the ovens (a.k.a. "boats").
These uses expose the material to lower temperatures than in the crucibles, because the wafers are solid, not melted.
Quartz is still used for these purposes, but in many cases it has been replaced with polycrystalline pure silicon, which can resist to these lower temperatures and it also cannot introduce any impurities. In comparison with quartz, polysilicon has the advantages of matched thermal expansion with the silicon wafers and of higher mechanical strength at high temperatures.
For a while a decade and a bit ago, there was only one operational, legal tantalum smelter on the planet - the others had been destroyed by the Indian Ocean tsunami or shut down over their use of conflict minerals and slavery.
I think there are now three - all on the ring of fire.
Then you’ve got stuff like cobalt, which we get at the whim of the DRC, a notoriously stable and functional state.
And of course, gallium, graphite, and rare earths, which pretty much all come from China. They could, at will, bring the global electronics supply chain to its knees.
I guess risk is everywhere, really, in our fragile systems.
Capitalism is fundamentally incapable of accounting for resiliency as it optimizes to cut such "dead costs".
That's because governments are run by the same braindead efficiency-first mindset these days.
It used to be easy to campaign on resiliency back when the USSR still existed - no matter what, all NATO countries had really large armies, months worth of stockpiles of everything from arms and munitions over medical supplies to food. Education was heavily invested in because the countries needed well educated adults to compete with the external threat. Companies kept stockpiles and had detailed disaster recovery plans and drills, not just for natural disasters but also for "how the fuck do we keep production running when the Red Army is marching towards the border" and "how the fuck do we transition from building cars and motorcycles to tanks and fighter planes when the Great War breaks out".
But once the USSR fell and the "end of history" was announced [1], all of that resiliency went down the drain - it was expensive after all and neoliberalism / "starve the beast" ideologues demanded that the "inefficiency" be cut to lower the tax burden on the corporations and the rich... and here we are, our education systems in shambles, companies got screwed left and right when covid hit and supply chains broke, and our societies in shambles as well as the people didn't have much reserves left after decades of wage stagnation and companies didn't either so they laid people off.
[1] https://en.wikipedia.org/wiki/The_End_of_History_and_the_Las...
Some people seem to run companies towards absolutely no slack at all, and are baffled by the idea of keeping some.
Reminds me of how bad pollution was in the GDR (communist Germany). You think capitalism is bad for the environment? Communism was worse.
Also, for fucks sake, look at the Western German Ruhrpott and the Ewigkeitslasten there. Or the open pit brown-coal mines - both West and East Germany have these, and they're a menace no matter where. All resource extraction is incredibly devastating, no matter if under communism, capitalism or anything in-between.
Open-pit mining holes and other permanent problems from mining like the need to pump out water to prevent flooding aren't really preventable except by not mining. It's mostly HOW things were done in the East that was worse. They had fewer spare resources to do things "nicely" and the state controlled both industry and the media (even the population via Stasi), so problems could be swept under the rug more easily.
But there’s nothing fundamentally that prevents pricing in risk of shortages to shareholders and appropriately stockpiling to mitigate that risk.
There is. Shareholders are just as likely to fall into the short-term gains trap.
I agree with you, in general, that the short-term incentives of our system encourage "optimization" away from stockpiling inputs, and that this is a worrying problem.
But I find it instructive to focus on and give credit to the long-term thinkers who buck those trends – and who have historically profited and persisted by doing so, by the way.
As it turns out, a bunch of manufacturers had independently discovered that by far the best source of them was a small company in Japan - unbeknownst to them essentially just one guy and his workshop. So everyone sourced it from him. Which was fine, until he took a holiday for the first time in a decade... Suddenly both original-source and second-source factories for some important chips were unavailable!
I'd love to know if anyone has more details, because I haven't had any luck with finding any reference to it. It's a story I read probably a decade ago, so who knows how many details I got wrong.
This is also critical for semiconductor manufacturing.
https://www.theregister.com/2022/03/11/ukraine_neon_supplies...
An even more obscure mine in Spain is used for the quartz to make the crucibles that hold molten silicon. For some reason its melting point is just far enough above that of silicon metal to make the process feasible.
1. https://www.amazon.com/Material-World-Materials-Modern-Civil...
High-purity quartz from areas like Spruce Pine typically forms in pegmatites, where slow cooling of magma allows large, defect-free crystals to form. Hydrothermal fluids permeate these rocks while they’re cooling, effectively leaching out impurities. If the geochemistry is just right, over millions of years, this process repeats several times creating very high purity quartz deposits that are very difficult to replicate in laboratory conditions.
Single crystal sapphires ~250kg are grown in production, so it should be possible with reasonable effort to do similar for quartz:
https://en.wikipedia.org/wiki/Kyropoulos_method
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Seems like it already is: https://en.wikipedia.org/wiki/Quartz#Synthetic_and_artificia...
No mention there of purity though.
I suppose the usual gem color arises from the impurities?
The crucible must be bigger than that. The crucible is made from fused quartz glass. So the mine does not need to have big quartz crystals. They must be only pure. The mined crystals are melted together and processed like any glass, except that processing quartz glass is difficult, due to the very high melting point and the high viscosity of the melted quartz.
The melting of the pure quartz requires itself a crucible made from materials that resist to even higher temperatures, e.g. a crucible of molybdenum or even a crucible of iridium, for the lowest contamination with impurities.
/? nanoassembly of quartz https://www.google.com/search?q=nanoassembly%20of%20quartz mentions hydrothermal synthesis,
Which other natural processes affect the formation of quartz and gold?
From https://news.ycombinator.com/item?id=41437036#41442489 :
> "Gold nugget formation from earthquake-induced piezoelectricity in quartz" (2024) https://www.nature.com/articles/s41561-024-01514-1 [...]
> Are there phononic excitations from earthquake-induced piezoelectric and pyroelectric effects?
> Do (surface) plasmon polaritons SPhP affect the interactions between quartz and gold, given heat and vibration as from an earthquake?
> "Extreme light confinement and control in low-symmetry phonon-polaritonic crystals" like quartz https://arxiv.org/html/2312.06805v2
"In conclusion – existing wafer inventory provides a buffer as mining operations restart, major companies are already using synthetic methods to produce semiconductor-grade quartz crucibles, and there are other sources of HPQ. Spruce Pine FUD is exaggerated."
"The Semiconductor Apocalypse No One Would See Coming"
https://www.viksnewsletter.com/p/the-semiconductor-apocalyps...
Would the loss of the North Carolina quartz bring a major increase?
It is said that alternative (higher cost) substitutes are available.
In this case you could almost look at it as climate change solving itself!