Is not each birth an independent random event, and thus the likelihood that they would have a boy, given that they already have a girl, simply 50%?
Actually, it isn't. More boys are born than girls. (However, boys are somewhat more likely to die young.) Also, the odds for a given mating pair are not the same as the odds for the population as a whole.
And then there's post-conception sex-selection....
But you're looking for at least one boy. If you had 1000 children, intuitively, the probability of at least one being a boy is huge.