As a firefighter/paramedic, pray tell, how would you suggest we "just get more efficient"? Part of the challenge is access, between heat and explosive risk.
It's not about being more efficient - it's about kicking out one or more legs of the fire triangle, with water, that being heat and oxygen. The problem is that physics dictates that overcoming the BTUs being put out by a battery fire requires rather a lot of water.
Use of other liquids to absorb this heat is ... problematic. One, you have to transport it to the fire, and two, runoff. It's bad enough having structure fire water runoff going to the ground and water supply, let alone another (most likely noxious) chemical.