My favorite is 1 mile = phi kilometers with <1% error
1, 1, 2, 3, 5, 8, 13, 21, 34, 55 …
21 km is ~13 miles, 13 km is ~8 miles, etc.
A 26 mile marathon? Must be ~42km.
Same for speed limits too; 34 mph is ~55 kmh
My favorite approximation is π·E7 = 31415926.5... , which is a <1% error from the number of seconds in a year.
(8/5)/(1 mile/1 km) = 0.9942; (1 mile/1 km)/phi = 0.9946. You're making things way harder on yourself for essentially no improvement in precision, especially when you're just rounding to the nearest whole number.