TVs are so predominant in our lives that room layouts and furniture are often designed around their presence. For example, the main TV in our house sits in a sort of built-in entertainment center/cabinetry. Making it transparent would be of no benefit. Also, many times people are hiding set-top boxes or media servers (and cables) behind the TV. Now those things need an aesthetically pleasing place to live, and cable management becomes 100x more important.
I can see applications for these, but it is going to require designing around them for maximum benefit. That will slow the adoption curve, which slows the price drops, perhaps keeping them in a niche segment for a long time.