Most of this is just bold claims without any backing. Every kid thinks they are the next Einstein, Jobs, or Gates. For the more technically oriented people, university provides the best environment for access to scientific papers and domain experts around. Hell, Thiel's own startup Palantir hires people "preferably with phd's." It's not the degree that matters, but what you learn during it.
Thiel has some form of political agenda and this is just a stunt to try and further it. I do not claim to know what his agenda is, but if I had to guess, I'd say his aim is to promote his libertarianism ideals.