I was once helping take down a 10-foot weather balloon full of helium, and took in two breaths in a row of pure helium. I started to get tunnel vision, said "whoah", sat down when I realized I was about to lose consciousness, fell down, and twitched just long enough for my friend to realize I wasn't joking around before I woke up. From my experience, hypoxia from pure helium is slightly pleasant all the way to loss of consciousness. I presume pure nitrogen would be nearly the same.
Let my last words be something witty in a high-pitched helium voice.
(Side note: pure nitrogen hypoxia would not be a particularly humane form of execution because the condemned would likely fight it by holding on to their last breath.)