Water-Splitting using natural sunlight is a difficult problem and many research groups at top institutions are working on it. The best known group in this field is Prof. Daniel Nocera at MIT. His research is being commercialized by the company Sun Catalytix and there are plenty of YouTube videos of him speaking and explaining his research. There are other research groups as well. The vision for the future is a distributed electrical grid. Each home or building would have a reactor on top that would contain a water-splitting catalyst producing hydrogen and oxygen gas, which can be stored indefinitely under pressure and then released into a fuel-cell device that would recombine to form water (that can be placed into the reactor) and electricity (for consumption). This would be an efficient way to capture much more of the sun's energy than current photovoltaics and is an entirely closed cycle.