Alternatively, imagine one car is parked (in neutral, with its brake off) and the other car hits it at 100. The center of mass of the two cars is moving at 50 both before and after the collision (conservation of momentum); after it, the cars will be moving at that average speed. The impact will again be equivalent to the original scenario.
The original claim probably results from a conflation of these two scenarios.
ETA: So what student drivers should be told is that hitting another car head-on is like hitting a brick wall at the same speed. For this to be exactly true, the momenta (mass * velocity) of the two vehicles have to be equal and opposite, but to communicate the general idea, I don't think we have to go into that.