To give some numbers, just the fixation takes 5.4 more energy, and photosynthesis is 6 times less efficient than solar panels. Moving to biological fixation would also increase water and pesticide usage
We don't want a Great Decarbonification Event.
If you remove all nitrogen from atmosphere, there WILL be consequences
Eliminating a gas while keeping all other partial pressures constant only affects physical processes. Biochemistry on the other hand only relies on partial pressures, and the number of organisms which interact with atmospheric nitrogen are literally so few that you could count them on one hand.
This is all pretty far afield though. There's no way biological processes are even going to have a dent in the ocean of N2 surrounding us.