Should've said function call not library call. My bad. Basically if you already have the linux/landlock.h, that should provide everything you need to do without explicit references to SYS...
This header defines the data types for the Linux kernel interface, but not how the syscall landlock_create_ruleset(2) will be issued. That is provided by libc either as a separate wrapper function (does not exist in glibc) or the implementation needs to use syscall(SYS_landlock_create_ruleset, ...), with the constant also being provided by libc. That is how it works for all syscalls and you won't be able to change this.