mplayer, for example, is just as capably at playing just about any media format, but is definitely far more user-unfriendly than vlc
Regarding user-friendliness they are about the same to me. Can you point out something that I maybe missed that makes mplayer "definitely far more user-friendly than vlc"? (not rude, just curious)
edit: missed a word
I feel that people too often confuse a user-friendly interface with an intuitive or noob-friendly one. But I guess seeing as most programs' user base's large majority are non-technical people that's fair.