He's really not owed anything. He neglected to collect his referral bonus it before leaving, bummer.
It would be like you being offered an additional 10k to do something for a client/boss. You did it, shortly thereafter left but hadn't yet received your compensation. You'd be within your rights to go after them via the labour board/a lawyer. If you don't see that, I don't want to know how you treat those around you.