Sure, if you manage to enter the character XeTeX will be happy to typeset it. It's not a LaTeX issue, it's an editor/desktop issue. I don't really know about maths, but I'm guessing keyboard input for many special symbols is hard. I use (Xe)LaTeX to input phonetic symbols, and I hung onto tipa (the LaTeX package that gives you IPA from ASCII) for a long time, until I discovered C-x RET C-\ ipa-x-sampa.