CSS Nesting is a huge deal for example, since it's one of those features that kinda made SASS and LESS useful to begin with, and (like variables) was always better as a core CSS feature than a preprocessor one. Always super interested in seeing what can be done with custom properties too, since that feels like a lovely next step after things like Shadow DOM and custom elements.
And popover is surprisingly neat too. The fact you can do these popup modals and things without any JavaScript now is super useful, and something that should finally stop developers wasting time with custom modals, dropdown menus, hamburger buttons, etc.
But I do wish that forms got a bit more attention from projects like this. The current status of them (wildly inconsistent in different browsers for many HTML 5 era fields, reliant on proprietary pseudoclasses being styled for display purposes, things being difficult to customise in general) feels surprisingly archaic for a platform that can let you do seemingly anything.