I think just about anyone who uses a name referencing an Array<Student> will give it the name "students".
And it does often end up mattering, for clarity where at its use sites where you won't have the type declaration to help you out, and for having "student" available as a name in the same scope, as it's typical to pull an item out of a collection.
/student/all looks particularly icky to me. For getting a student, it seems unlikely that we'd identify one using these words, but in other domains, they may end up conflicting with another resource. Whatever you end up doing about that, it'll surely be gross.
I think plurals are better so nyah! Heh.
Also, it's totally my job to get hung up on these kinds of details. Clarity, avoiding collisions, enabling easy expansion, and especially averting future breaking changes to deal with the aforementioned matter to others.