You can't legally break into the business, but DIY on your own house is entirely possible: the equipment is available for 1/4 to 1/3 of the "installed" price and some of the more climate-friendly refrigerants do not require an EPA license to purchase.
Yes, the work involves electrical, light plumbing and welding, a specialized tool or two, attention to detail, and definitely physical labor, but for a lot of engineers that's just fun stuff to do on a weekend - really fun stuff when you save over $10K per installed system (at the 3-5 ton unit capacity level.)