Not concisely in the general case, but in this case the difference is fairly straightforward - CI/CD doesn't affect the structure of your executing application at all, only the surrounding context. I don't want to spend the hours it would take to characterize architecture as distinct from implementation, but the vast number of textbooks on the topic all generally agree that there is one, though they draw the lines in slightly different places.
> I think what you're saying amounts to,
Very much no - my point is about the process of implementation. The services.. _do_ enforce boundaries, but the boundaries they enforce may not be good ones.
In order to successfully extract services from a monolith, you have to go through a process that includes finding and creating those domain boundaries for the domain being extracted. If it's your first time, you might be doing that implicitly and without realizing it's what you're doing, but under the hood it's the bulk of the mental effort.
The part where you actually _introduce a service_ can be anywhere from a tenth to half of the work (that fraction varies a lot by technical stack and depending on how coupled the domain in question is to the central behavioral tangle in the monolith), but by the time you've gotten the domain boundary created you've _already solved_ the original problem. Now you're facing a trade of "extract this well-factored domain out to a separate service application, to prevent its now-clear boundaries from being violated in the future". And I contend that that's a trade that should rarely be made.