No, the range is not 100 miles. Even 10,000 pound vehicles can go 300 miles these days, like a hummer.
Ford is 100-126 https://www.ford.com/commercial-trucks/e-transit/
If we are talking about just an ambulance, the range could get higher, but there are diminishing returns eventually for a giant square so it probably needs an aerodynamic redesign.
I thought the question wasn't about the delivery vehicle, I thought it was asking about rivians in general. There's nothing limiting that range inherently, it doesn't have the greatest aerodynamics, but the goal is carry all those packages.