In the late 1800s - early 1900s this was done along many riverside cities in Eastern US and Canada, because of cheap hydro power generated by dams.
In the late 1800s - early 1900s this was done along many riverside cities in Eastern US and Canada, because of cheap hydro power generated by dams.
"In their search for a new process for producing cyanides for cyanide leaching of gold, Frank and Caro discovered the ability of alkaline earth carbides to absorb atmospheric nitrogen at high temperatures."
This 1913 book on calcium cyanamide manufacturing explains:
https://archive.org/details/cyanamidmanufact00pran/page/4/mo...
Nitrogen is obtained either by fractional distillation of liquid air, or by means of the copper oxide process. In the latter, air is passed through a red-hot mass of finely divided copper, suspended in asbestos or other inert material. The copper combines with the oxygen and allows the nitrogen to pass through. The copper oxide is easily recovered for use by reduction in situ with a suitable gas, such as natural gas.
The nitrogen used must be pure and dry, otherwise, at high temperatures, there is destruction of the carbon pencils, and of calcium carbide, according to the following reactions ...
I was thinking, surely they couldn’t be distilling air in large quantities in the early 20th century. But, yes!
The other, copper reduction method also sounds pretty intense.