Further: There are no circular (2D) molecules; nature prefers hexagons and other polygons for that. Even the proton isn't perfectly spherical. Whether the electron and other subatomic particles are perfectly spherical cannot, as yet, be determined. (The electron seemingly has a diameter far below the Planck Length.)
There are no very large circles or spheres, either. All astronomical bodies are somewhat flattened.
So I dare say perfect circles and spheres do not really exist, save as idealized mathematical objects.