I would suspect you're right on simpler being better here. That doesn't mean this isn't worth exploring. But one practical tradeoff calculation to make to see how viable this is right now is take the component cost of the cooling system and put that into more "simple" solar panels and see what trade of power generated is.
If that benefit isn't a win of the cooling system, then a lifetime reliability of the cooling system being less than a lifetime reliability of the solar electric components can only make that tradeoff even worse.
But making that calculation might still give someone a target for cost, performance specs to become a viable market option.