Could the world go PFAS-free? Proposal to ban ‘forever chemicals’ fuels debate
nature.com
nature.com
The reason is PFAS pollution, where the levels in the water table now indicate the potential for bioaccumulation above the recommended level for human toxicity. The people living in that area are now denied access to clean water and not having to worry about eating toxic fish, and I'm sure the otters and herons in the area haven't gotten the notice. Millions of state tax dollars have now been allocated to try to just estimate the contamination level in drinking water wells throughout the state as well.
Frankly, the producers and users of these chemicals have proven to be, at the minimum, so grossly negligent and potentially actually malicious, that they can not be considered to be acting in good faith, and "reasonable compromises" should be looked at with extreme suspicion. I feel the responsible organizations fined for both remediation and damages, the individuals responsible made criminally liable for the harm they've caused, and once that example has been made, we can talk about compromises once the "free market" has factored in the actual cost of using these chemicals when they can't just dump risk onto the public.
[1] https://ctmirror.org/2021/08/29/how-widespread-are-pfas-chem...
The story changes a little when you get to Lake Michigan, which is more heavy metals, fecal coliform, etc. The heavy metals coming from the steel refineries who periodically have oopsies and dump a few tons of waste into the lake.
The stuff is everywhere. At least the raw sewage overflows from Milwaukee/Chicago mostly dilute and turn less toxic in the matter of months versus generations as is the case with PFAS.
Swimming advisories were only in effect for a few hours after the lock was open for nearly 8. Things are getting better but we still have work to do.
The maximum safe concentration of PFAS/PFOA has been reduced in the past years, due to better understanding of health concerns.
As a result and due to more public attention, water surfaces are now seen as harmful up to 10 miles away from the factory. The factory is located right between a medium sized city and a national park. Within a radius of a mile around the factory, people are advised not to grow vegetables.
I think many countries have similar stories and clean up costs are going to be huge.
Steel mills or petroleum refineries. We have both.
I thought that mercury in the environment came mostly from coal fired power plants. The mills have their share of pollution issues but I think that's more air pollution. Well... There was the issue with killing a bunch of fish a couple years ago. IIRC that was cyanide.
The protections provided to corporations are intended to shield hands-off investors, not executives and board members that drive profit above safety and common sense. I'm not in favor of a lot of heavy handed regulation, but I'm all for corporate liability.
I wish we could do it for officier of corporations. Now that they enjoy free speeches privileges.
"Wait a minute your honor, here's my newborn child; he's the legal owner of that truck, and therefore he's the one that should be locked up for running over the old lady."
If you gently poisoned millions of people, entirely on accident, as a private citizen, you would never see the outside of a prison. If you incorporate and claim it's a standard part of your business, you won't even lose your private mansion. Judges have significant leeway in piercing the corporate veil and depriving bad actors of their ill gotten gains, but they don't. The US DOJ has significant leeway to go after companies aggressively and really push for seizing assets of criminals, a cop literally doesn't even need a real justification to do it, but they haven't since Enron.
We've had forty years of the only "punishment" for doing anything wrong as a company being a 1% of ill gotten gains fine, even though none of the actual underlying laws have changed to cause this reduction in punishment. This has been an entirely internal choice. Of course this results in companies largely not giving a fuck about anything that isn't profit.
Imagine a bunch of college kids running around water sources with unclear intentions.
Oh wait, you don’t have to imagine. Look at the saint Soline movement in France. Those people try to keep rain water accessible for all. ( as oppose to massive rentension basin for corn only )
Result : they are eco terrorist and should be meet with large deployment of hostile police force. ( thousand of flash ball and tear gaz grenade fired in one single night )
Unfortunately, even what happened in East Palestine was just a slap on the wrist compared to the damage it caused to the affected communities.
Corporate liability needs to be ratcheted up several orders of magnitude before we’ll see any actual change. As it stands, most governments have no teeth against corporate greed and exploitation.
As an aside, I sometimes think public defenders and prosecutors should come from the same pool of attorneys, held to account for striking balance instead of just W's to one side or the other.
It's arguments like that where I wish judges and the court system as a whole could do something like finding that an argument was in complete bad faith and fine the companies and lawyers just for having the gall to make it. ( I know it's a pretty bad idea in reality but that and some of the lies told to get mergers through are just infuriating)
Even if you have dedicated prosecutors who are able to oppose moneyed interests, the law gives corporations huge tools to wriggle out of suits.
Perhaps fines should be levied against those that held voting rights.
What you see in industries such as mining where corporate liability is technically far less forgiving is that this concept of limited liability implies that a network of corporations can play musical chairs with hard-to-predict risks - essentially abusing bankruptcy and the general difficulty in enforcing liability via the courts even in the best of times to achieve not merely limited liability, but intentionally reduced liability. Since much of this is just a bunch of man-made rules, of course we're all going to game them to find the particularly profitable loopholes; this is inevitable. If it's not pollution, it's lobbying. If it's not lobbying, it's privatizing infrastructure at exploitative cost. If it's not physical infrastructure, it's owning social infrastructure, i.e. platforms. If it's not platforms, it's an incomprehensible spaghetti designed to evade or avoid taxes.
Regarding corporations as equivalent to natural persons for many legal questions was a huge mistake, and needs to be reversed. I'm not particularly hopeful we'll get there without a literally bloody revolution, or by losing a war, or some similarly horrifying discontinuity of modern life.
Allowing people to cooperate under some legal entity is a great idea; allowing capitalist incentives to optimize those a reasonable idea with some risks (but hopefully manageable ones). But doing all of that at essentially no cost, little oversight, lots of loopholes, very little transparency, very limited liability, legally not just unrestricted but even protected "speech" and with arbitrary nesting has to be one of the most idiotic things we've come up with in centuries.
Isn't it a bit early to make that conclusion, especially since all the legal action hasn't concluded?
3M is filing for bankruptcy due to PFAS litigation, and even then they can't cover the costs [0] This doesn't work, the damage is already done, and the profits have been pocketed. What's worse with PFAS for environmental pollution is that no mechanism for clean up currently exists.
> criminally charge the decision makers for cases of negligence.
Might work as a weak extrinsic motivator, but there's plenty of "hot potato" going in this kind of work. It's also hard to prove negligence when the "decision makers" are ignoring the environmental costs through either wilful ignorance, burring their own research, or through optimistic interpretations which give them plausible deniability - combine that with shared responsibility and it gets hard to point the finger at individuals unless you were in the room. It's hard to pin down a "decision" of inaction.
We either need some kind of intrinsic motivators, i.e make it in the interest of corporations to protect the environment. Or really heavy legislation that requires extensive proof of ecological safety for every new chemical dumped into the environment rather than the current "we'll figure it out later" model.
[0] https://news.bloomberglaw.com/environment-and-energy/3m-head...
Are you suggesting that 3M should continue to operate as if they didn't poison the world? I'm fine with them being bankrupted by the lawsuits. Let it be a warning for the next company.
1. If the damage done is so severe that it's impossible or impractical to reverse, then even in the case of recovering 100% of the profits ever generated, it still won't be enough to fix the damage. A larger long term environmental cost for the many has been traded for a far far smaller short term financial reward for the few.
2. As the sibling commenter pointed out, companies can be used as a financial liability shield, just pay yourself an absurd salary, keep liquid funds and reinvestment low (especially when the game is up), and all that's left is a functioning but otherwise empty husk.
>We either need some kind of intrinsic motivators, i.e make it in the interest of corporations to protect the environment.
You do this by deleting any company that shows itself to be poor stewards of the environment, and making sure it really really really hurts, financially, for the ones who profited from it, including high level management. "Just doing my job" shouldn't suffice when your job is overseeing a chemical of unknown danger.
When involving yourself in an unethical company means you lose your fortune, the incentives will be aligned. If that means rich people do extensive due diligence before involving themselves in anything, surely that's a good thing right?
That seems like a nightmare in from a regulatory compliance point of view. You could do all the required research that the government wants you to do, and still get personally punished a few decades later if it turns out the product was harmful.
Even putting aside the problem of implementation, you also need to consider the second order effects. Specifically, impact on the development of new technologies. Why would anyone want to commercialize any new technology when it can set them up for unlimited personal liability in the future? Remember, the whole point isn't that just the company has to pay for their damages, it's their shareholders and corporate officers will personally held liable for damages as well. How are you going to get innovations in fusion/ai/superconductor when all of them will be subject to the threat of arbitrary and retroactive punishment in the future? For instance, you create an generative art AI startup today. Presently there aren't any regulations, so you do the bare minimum of due diligence. This seems reasonable, given that it's not really like chatgpt so the chance of AI takeover is low. Three decades down the line generative art AI becomes a hit and millions of artists around the world are unemployed. They lobby the government to prosecute you and your shareholders for putting them out of work, arguing that you "CHOSE not do enough research beforehand to be aware of dangers". Does that seem like a fair risk to subject the founders to? Do you think this is a worthwhile trade-off between innovation and conversation?
The onus should ALWAYS be on you PERSONALLY as someone being PERSONALLY enriched by the company you own and or run, to not poison the world. If you are worried that it will eventually come out one of your products is harmful to the environment and yet you've basically dumped it everywhere, maybe do enough diligence to convince yourself that you will be safe, or DO NOT SELL A DANGEROUS OR POTENTIALLY DANGEROUS PRODUCT TO PERSONALLY ENRICH YOURSELF TO THE TUNE OF MILLIONS OF DOLLARS
Why should businesses exist solely to enrich their owners at the expense of the average human? Doing so should be one of the most heinous crimes.
Employees need corporations to generate profits, otherwise there are layoffs or closures and people lose their jobs. This is bad for the people because we have limited social safety nets and joblessness can devastate people.
People who hope to ever retire need corporations to generate profits, otherwise their 401ks can never grow. This is bad for the people because without investment growth it is unreasonable for a most people to generate the sums needed to retire with dignity.
We've generated a system where the people will complain when corporations are held to any account. We've tied ourselves to the success of big business and can't get off the ride.
Maybe I would have more respect to whatever free market proposal if the real cost were factored in.
And yes, it’s including not polluting or cleaning up fully after yourself if you do.
If you pollute in a non cleanable way, you either pay a lot, or it’s illegal.
Kinda tired of freeloaders.
I believe it should be normalized that we speak about the most egregious, permanent, impossible to reckon with environmental pollution in the same way - that is - it ought to be a crime to pollute in the most serious ways and that crime out to be punished with state executions.
All these articles in mainstream papers the last few years fomenting a panic about rising crime, calling it crime waves, etc. They are not talking about this. Because they don't mean this. We don't, for the most part, consider these to be crimes. Sometimes we may use that word, but you don't see the same flood of op-eds and public official press conferences calling for retributive justice.
Similar shit elsewhere. Shoplifting is a crime but hundreds of millions in wage fraud is just bad accounting, etc etc.
Maybe calling it corporate bioterrorism (though a bit hyperbolic) could shift the overton window into somewhere closer to reality.
When Congress continually undermines and rolls back the agencies rules, who actually is to blame? The regulator? Congress? The voters?
The point I'm trying to make is that this scenario isn't as black and white as one might think. It's easy to be an absolutist about it when it's not your child burning to death.
For some reason, even though plenty of people are ready and willing to buy and sell murder, we still don't allow it.
Both can be bad and disallowed.
The US government knew it was bad, bought it, and then knowingly created the vast majority of contamination.
They then Sue manufacturers like 3M, while continuing to buy and use it and cause more contamination.
It is like buying a knife, stabbing a bunch of people, then suing the manufacturer while still running around stabbing people. It screams of misdirection.
Why is that?
PFAS firefoam is still widely used, as governments still deem it necessary. However, training with real PFAS fireform is now more restricted than it once was.
Do you have numbers to back up your assertion?
Scroll through these 180 pfas contamination Superfund sites and count how many are government facilities versus private companies.
https://www.epw.senate.gov/public/index.cfm/superfund-sites-...
If you want to get technical, this paper estimates the impact of different sources, Comparing airports and military sites to Major PFA industrial sites. There are ~350 PFA sources from airports and military, and 7 from industry (including 3M!).
The individual military and airports released more PFOS per SITE than industry.
The industrial sites are associated with about 5X the PFOA in the local water. However, we are still talking about 7 industrial sites vs 350 airports and military bases.
For example, if it's for space satellite parts, or for nuclear energy application, etc, when alternatives don't exist as long as the quantity are small and as long as they're being disposed of safely.
So in short: if it's a sector that is high value enough, where quantities are small and where safe disposal is mandatory.
You have no natural right to a profit at other's expense, and we should stop pretending that these companies are following the rule of the law with these settlements. No part of any law says you have to let malicious companies continue to operate because they are big and have a lot of money. Bankruptcy is an important and necessary part of a healthy market.
Another thing is that the stock market doesn't work here. It promotes shortsighted trading without an eye for long term side effects. In principle shareholders should be accountable too. If you owned stocks of a company that caused damage during the period when that damage occurred, you should be accountable and at least you should not be able to profit from it. The stock market should be retrofitted with an accountability system. This is the only way shareholders will start caring about our future.
If there's no incentive, it's empty desire or based on some fantasy that government would suddenly operate in terms of what's best for society rather than a serious consideration of how power works. Why look to government to do that?
Are examples of government pollution controls effective, or examples of greenwashing? For instance a lot of the Quebec forests that burned already contributed to those CO2 offsets by having someone say they wouldn't burn them, and yet...
Plus, I like to think that IT can save the world :)
You assert this without elaboration. What makes you think that? Maybe the average wall st trading firm doesn't care, but institutional investors (eg. pension funds, university endowments, family offices, sovereign wealth funds) would very much care if their holdings go up in smoke a few decades from now.
Nope
Any fund has nearly constant review of their holdings (and certainly scheduled periodic reviews), which would highlight issues with any of their holdings. Moreover, there are many hedging strategies. It isn't like companies with these kinds of externalized risks go poof in a minute. The problems, especially legal liability, become evident over the course of years, and the funds can an do adjust to not take the losses. Anything less would be a breach of their fiduciary duty to their shareholders/investors.
It allows a one sided bet. Things go well, I’m rich. They go very very badly all I can loose is my investment.
Not saying its good or bad - just how it seems. Companies out of the limelight and too small to notice have more leeway to cheat.
>smaller businesses creates more limited liability. I.e less to lose more to gain by being bad stewards.
Nonsense. A thousand small CEOs have limited liability to not lose their sole home if they do bad things that harm everyone and get shut down. A single Giant CEO has limited liability to go back to his six mansions in his chauffeured lamborgini that picked him up from his private plane.
You mean like Big Tobacco? They survived their lies and cover-ups, and are still around and doing well.
Consumers cannot determine if they have "forever chemicals" in their products and vote with their wallet.
I've tried for ages to find cookware that is healthy, and time and time again the cookware I've bought has these chemicals hidden behind corporate lies.
Even consumer's reports has finally realized:
Because CR’s tests and research show that even products made without PFOA may contain the compound because of how they’re manufactured, we have decided to no longer display "PFOA-free" in our ratings of nonstick cookware. Such claims may not be reliable for PTFE-coated products.
happily there is hope:
A California law that will go into effect in 2023 will ban companies from claiming in online sale listings that a cookware product is free of any one PFAS—like PFOA—if it contains any other PFAS, like PTFE. Those claims will have to be removed from packaging by 2024, when a similar law will go into effect in Colorado.
I wonder if "online sale listings" will just use geoip and ignore the rest of the country.
Here's an amusing article highlighting the struggle to single out the "bad" PFAS from the truly life-saving PFAS. https://www.bu.edu/sph/news/articles/2022/is-there-a-right-d...
It’s the same all over, companies care about their own short term profits and gladly maim people and things for a buck in their pocket.
One of the interesting side effects of free markets is that when there are no consequences for mass poisoning / polluting, you will ignore opportunities to manufacture without doing so because there is often zero or negative economic consequences to change your process.
In DuPont’s case, it was more valuable in the near term for the shareholders to ignore this manufacturing innovation and not disrupt supply than to reconfigure with a new process. No doubt there were massive risks involved in trying a new process that made it a “safer” and wiser decision economically to continue to use PFAS.
I think about this every time someone tells us on HN how a freer market will solve our problems.
How is that possible? PTFE (teflon) is itself a PFAS, no? Did they "only" get rid of other PFAS used during the manufacturing of teflon?
“Teflon is a high molecular weight polymer made using perfluoronated surfactants. Technically, PTFE is a fluorine-containing material but it is not the PFAS pollutants of recent concern. In the conventional synthesis, the real source of PFAS pollution is primarily those surfactants used in its manufacture. Our process made the use of those surfactants unnecessary.”
Why do you DuPont never acted on your patents?
“It was a cost of business decision because they had already invested so much capital in making Teflon with those surfactants.”
https://news.ycombinator.com/item?id=36961328
Getting a product like this stood up is a $100 million endeavor at minimum. That’s before customer #1 presses “buy.”
My father and the colleague I mentioned are both successful serial entrepreneurs (large exits, Sequioa backed unicorn, etc.). There is close to zero appetite from VCs in this.
VCs seem to be allergic to these CapEx intensive businesses and I don’t blame them—the risks are enormous when compared to something like a SaaS.
That said, if you know someone who’s dying to throw hundreds of millions at this problem, he’d probably take the intro. You can email me at super solenoid theory at gmail dot com.
I think you'd get seed money, and a network large enough to raise some serious capital in future rounds.
There is a gulf of value between "literal cure for cancer" and, like, some basic consumer good. Most things do not exist at either extreme end. Not all things worth doing are wildly profitable.
They even had a process to remove the radioactivity, but, it made the nicotine a little less addictive so they didn't do it. Instead, they kept marketing to children with cartoon characters for another 20+ years until forced to stop.
These same companies are still marketing cigarettes to kids where they can get away with it.
At some point we need to start talking about self defense from this shitty system. And I feel like that point was the 60's.
But the reason they haven’t been acted upon (that I know of) is that economic difficulty of making a competing Teflon has to do chiefly with issues of manufacturing scale and large up front capital expenditure. This is true across the entire chemicals industry for any new product. Rule of thumb costs were, the last I heard, roughly 100 Million in development to get a single product into baseline commercial viability.
Why compete against an established and “tainted” product like Teflon? Can you guarantee the PFAS free process is cheaper at any of the initial commercial scales you’re likely to achieve? Is there a market for an off-brand substitute?
These kinds of risks delimit innovation in physical manufacturing far more than the possession of IP.
They already do this for Schedule I drugs (not that I agree with that either). They finally got fed up with adding new designer drugs to the schedule, and there's an entry that says something like "any similar chemical substance that causes the same pharmaceutical effects as a Schedule I drug or is used for such effects or has a similar chemical structure".
I definitely don't agree with that clause when it comes to drug enforcement, but if a good case could be made that PFAS should be banned, then adding that clause to preemptively block PFAS-alikes that are just a couple atoms away from the original formula doesn't seem excessive to me. And, if somehow it should be excessive (the change fixes all the problems we might have with PFAS substances), then let them argue that to Congress.
Exemptions for producing small amounts for research, obviously.
If Congress didn't do this, if they're not doing that... then they're just bad at the one thing they're supposed to be doing: writing effective legislation.
It will be written by think tanks behind lobbyists for industry interests that donate to campaigns.
> the one thing [Congress is] supposed to be doing
. . . is getting reelected. We do not elect them because of competency in law-writing or even in voting for their constituencies' interests. We elect them because they spend lots of money to tell us how monstrous "the other choice" is.
The problem is that these PFAS chemicals do things that are useful, and banning any future useful inventions isn't nearly as desirable.
Let industry and the courts argue what exactly harms the environment or is too similar. But industry will think twice about using anything similar because to do so they'd have to take on a court battle to prove whatever they decide to use isn't harmful despite being similar.
https://en.wikipedia.org/wiki/Federal_Analogue_Act
Or instead of outright banning pass onerous taxes so that it’s only used in applications that absolutely must have it and not every throw away piece of clothing and wrapper.
Giving the DEA or another executive agency more authority here seems like a terrible idea but sometimes I’m not in the majority and I understand that.
The hard part, I suspect, will be regulating all the different forms of "forever chemicals" and not having it be a perpetual game of whack-a-mole where chemists figure out ways to slightly tweak the structure of the chemicals so that they effectively replicate the function of PFAS without triggering the definition of PFAs. We're already pretty hooked on the usefulness of PFAs for all sorts of stuff (clothes, containers, etc) so going cold turkey is going to require some sacrifice.
source?
https://www.foodpackagingforum.org/news/study-finds-plant-ba...
>Thirty-six of the investigated brands contained detectable PFAS, among which perfluorobutanoic acid (PFBA; CAS 375-22-4), perfluorooctanoic acid (PFOA; CAS 335-67-1), and perfluorohexanoic acid (PFHxA CAS 307-24-4) were the most frequently detected species.
That's not the same as "They release 95% of the pfas in the drink".
I understand the concern, but I guess I don't understand the risk yet. My understanding from chemistry class was that PF- compounds are so useful because of how inert they are. Their indestructibility is what makes them mostly harmless - if you eat a pile of (room-temperature) Teflon, it just goes right through your body.
Getting a $20 Teflon pan instead of a $15 one but they actually dispose of the chemicals properly seems like a no-brainer here.
It's waterproofing that's the problem - for example paper straws.
No but PFASsen are used (and typically discarded poorly) in the production of Teflon.
My preferred pan for fried eggs is stainless steel. With plenty of butter the eggs crisp up and release from the pan with no stick at all. The only real trick is to not flip too soon.
Do you manage to get a runny yoke?
I legit went through 2 dozen eggs trying to get a perfect fried egg on stainless steel. I tried everything - hot pan, cold pan, oil, butter, swirling the pan, a touch of vinegar. I could not find any combination that worked - I suspect that you either have to have very particular equipment.
SS easily heats but easily cools.
You can cheat with a lid - just seconds the whites would be in your preffered condition (ie with/out crust) cover the pan, sing aloud 'We all live in the yellow submarine, yellow subma' and move the pan off the stove, but don't let it rest under the lid too long! In 20-30 seconds it would catch to be the nice, yet runny one, but anything longer and it would be more thicker, though if you like subs/burgers with eggs - it's a way to it.
PS you can sing something more palatable for you, if you wish *grin*
Most range levels can get to this point, even medium-low, but you need to leave the pan on the heat for some time before starting to cook.
I suspect that equipment is a huge factor. My $20 stainless steel pan might not have the right surface characteristics.
nit: yolk
For the most part, cleaning the cast iron is two seconds of chain mail scraping under the faucet because not much really sticks to it and there's just the small leftovers that weren't worth scooping, then I put it on the stove for a minute or two while I wipe up other things and just let the water evaporate off so it doesn't rust.
I like sticking mine in the oven and letting it preheat to dry them, plus it's genuinely pretty convenient to store them there when unused anyway.
I hate frying eggs on cast iron. I need to wait so long for it to come up to a reasonable temperature, it always seems to overcook the whites and leaves the yolks cold. Every time I mention having trouble with cast iron, people jump out to tell me I'm holding it wrong and it's so easy, but it's really a finicky way to cook.
However, a seasoned stainless steel skillet is a lot like an aluminum teflon skillet except that it doesn't care if you heat it too hot, in my opinion.
https://www.lodgecastiron.com/product/carbon-steel-pan?sku=C...
This is a myth. I was struggling with getting a good non-stick-ability on my Lodge, until someone pointed out the 'patina' is really just burnt carbon and does nothing for non-stick. The non-stick seasoning comes from polymerized oils, which aren't affected by lye-free soaps. I haven't had any sticking issues since I've started washing my pan with soap after a messy meal and leaving a microscopic film of Crisco on after drying.
The soap myth harkens back to the day when soaps were actually pretty caustic - they were lye based formulas that you had to use gloves to wash dishes with. That stuff would eat through enamel.
Non stick, easy to clean, durable, good temperature properties.
I have this enameled cast iron pot that I cook just about everything in - but it just destroys eggs.
And from what I've seen, while charred food is carcinogenic, eating an entire course of badly charred food is like an order of magnitude less carcinogenic than smoking a single cigarette.
Teflon pans are also mostly harmless unless you overheat them by a lot (i.e. forget it on the stove, empty and on high heat), it is the large scale accumulation of manufacturing byproducts in nature that is the problem.
Don't call for the meme that saturated fats are bad. Butter is safer than unsaturated fats which change when heated.
Thank you, I was unaware of that. Important to note that it happens only when the pan is grossly overheated (280C/580F) [1]. For reference frying an egg is done at 300F.
Still a concern, it's not that hard to imagine being distracted and leaving an empty pan on a coil set to high, it will likely reach 600F after a few minutes.
1. https://vcacanada.com/know-your-pet/teflon-polytetrafluoroet...
Do you fast fashion Nikes or bicycle chain lube need PFAs? No.
The hysteria surrounding PFAs is going to be a net harm, and some politicians need a wedge issue to vault themselves forward in the media spotlight to buy votes.
Reading the HN comments today is sad. I thought this was a science based community.
RE: HN, it has grown and been redditified a bit, rash downvoting, sarcastic non-sequiturs all abound.
There is no possible way a durable water repellent (DWR) coating will last decades on a jacket, with or without PFAS. Modern outdoor apparel simply isn't designed for long term durability - it's designed for flashy marketability, because the externalities don't have to be priced in. There are a few exceptions (e.g. "true" softshells like Buffalo jackets) that have never, and will never, see mainstream adoption.
During the discussion the environmentalist said to the effect "we're working towards eliminating (banning) chlorine from the planet". We were so shocked at what she said that we decided never to mention the element by name again and only referred to it as element 17.
This experience was a salient lesson what can happen when ignorance and popular notions mix. No doubt PFAS-type chemicals have been grossly abused as were CFCs and they need tight regulation but as we saw with the Montreal Protocol simply banning most CFCs outright rather than introducing strict regulation caused many problems. This led to certain chemicals becoming unavailable that had no effective but 'safer' equivalents and this has been problematic. Even now, I know of people who still have drums of CFCs which they almost guard with their lives—they won't even part with an ounce of the stuff for love nor money because when gone it's the end of the line.
It doesn't end there, in recent years we've seen certain CFCs being released to the atmosphere from illegal manufacturing in countries where monitoring isn't strictly controlled. Like illegal drugs, if there's sufficient demand people will supply them. Banning over 12,000 chemicals outright without a full and detailed investigation is certainly to cause similar problems.
We should learn from the CFC experience and take a carefully measured approach. Careful and strict regulation is likely a much better way of dealing with the problem..
I wonder how long it will be before we'll have to start whispering 'element 9' in hushed tones for fear of those who would wish it banned from the planet.
Don't we? I've got a bunch of non-stick pans that I love cooking on (I checked the brand I use most, and their pans are coated in PTFE, a PFAS). I've also got a roll of PTFE tape for plumbing around the house (basically ubiquitous for that purpose), and some PTFE tubing for hobby use (PTFE tubing is in the majority of 3D printers).
I'm as or more concerned about the plastics in food packaging myself. Hard to avoid with so much processed food in most grocery stores though. Wouldn't mind taking a few steps back. Considering we grow well more than enough food to actually feed the world at this point.
At the same time I don't have to worry about nicking or overheating the teflon, and stainless steel pans tend to have better heft and thicker bottoms.
I know we live in an AI post-search-engine world but...
I don't think 99% of people ever get their cookware that hot.
Anyway, a colleague caught it in his hands which was surprising given he wasn't that nimble. The bird didn't appear the least bit sick and he likely caught it because it was used to having people around. The aim was to return it to its owner if we could find the person (it was an industrial area but there were many homes in the street). Incidentally, we weren't bird owners so managing a lost bird was a new experience.
We borrowed a largish birdcage that hadn't been used for years, cleaned it up and bought special canary feed and a cuttlefish etc. from the local pet shop, and we hung the birdcage and canary in a partly-shaded area without direct sunlight just outside the factory door with a sign on it to the effect 'do you own this bird?'. Every night we brought the cage in and covered it with a sheet just as I'd seen my grandmother do with her canary when I was a kid.
This went on for about two weeks or so and the bird seemed well and healthy—and we'd gotten quite used to the bird happily chirping away outside the front door. One day I noticed fruit flies around a garbage can inside the factory area and sprayed inside it with normal household pyrethrin-type insecticide which is usually pretty innocuous (at least to humans). Moreover, I was well aware that the canary was in the factory albeit 40/50 feet away so I was careful and deliberately confined the spray to inside the garbage bin.
Next day when I came in I found the canary dead at the bottom of its cage and I was considerably upset over its death as I'd not only gotten used to having this cute little creature around but it was immediately apparent to me that my spraying could have been the cause although I just couldn't see how such little amount of spray would have traveled that large distance.
It would be interesting to know exactly how sensitive canaries are to pyrethroids and how others manage to keep their pet birds safe in these circumstances.
Fluoropolymers and fluorosurfactants have unique properties that make them very difficult to substitute. I'm not sufficiently informed to comment on the possible health impacts of fluorinated hydrocarbons, but I can say that a world without them will be poorer in countless small ways. That might well be a price worth paying, but we shouldn't pretend that it's an easy decision.
What I was thinking of is the claimed "PFOA-free" on some new cookware is the same as "PFAS-free" which it clearly isn't.
Though PTFE is so inert, I don't think it faces the same problems as PFOA and other PFAS used in firefighting.
Before someone claims to the contrary - I basically only use TWO pans now for all my cooking - both 14" carbon steel pans I initially conditioned that have only gotten more non-stick as I've used them. I regularly cook over-easy eggs, scrambled eggs, and other foods that are apparently only possible in teflon non-stick pans if you believe the literature.
Before putting in your eggs, heat up the pan and put in some oil/butter. A spatula that can scrape well (flat-nosed, or moderately flexible plastic/silicon) is also helpful.
For a spell some years back, I had a game of "find the worst pan in the kitchen and see if I can cook my eggs without them sticking". Not quite a 100% success rate, but pretty close. (That was mostly scrambled, though. Fried eggs and omelettes are more difficult.)
It's true that a non-stick pan makes it much easier a beginner, but the downside is that said beginner will destroy a non-stick pan within weeks.
[1] https://www.victorinox.com/us/en/Products/Cutlery/Accessorie...
[2] https://www.nytimes.com/wirecutter/reviews/victorinox-slotte...
There is. Seasoned cast iron.
The problem with cast iron is that it requires work to season it properly and maintain it. People are lazy.
> There's no good substitute for PTFE in rain clothes either.
They used to use oil and wax. They were called oilskin coats. I'm not sure if it's because they are niche, but now such coats are pretty expensive. Problem: Cost.
So you're right in some sense - the alternatives don't provide us with the same level of cost and convenience.
Oilskin coats are also much heavier and less effective at keeping out water. The main problem isn't cost, it's that they're much worse as rain wear.
I cook a lot, and I have no interest in non-stick cookware.
The only way I've heard of people screwing up is by to using it infrequently. If you season with canola or vegetable oil, and use it every time you cook, then the patina takes care of itself.
To clean, scrape using chain mail or a plastic scraper, such as the ones from pampered chef or lodge, and be sparing with the soap. Do not put it in the dishwasher.
If you ignore the above, then scrape off as much of the old patina as possible, then coat lightly with oil + bake at 300 for an hour.
Compare the above to non-stick, where getting it near anything sharp destroys the pan, and you have to buy a new set every 1-5 years. Re-seasoning a pan is much less effort (and cheaper / more environmentally friendly) than shopping for a new one!
Also non stick burn when they get hot which is an awful trait in a pan. I cook some insane fish and beef and it is the most braindread process with a cast iron.
I don't think the issues for the well-known brands have much to do with the materials. Instead, I think it's because there are a few traditional brands using traditional (non-optimized) production techniques, then charging large margins.
That's fine if you want to pay for the best of the best, but it would be nice if there were a bargain route too. e.g., for iron cookware, two good brands are Lodge and La Creuset. Heirloom-quality Lodge pans start at $25; La Creuset is many times more expensive because of the [traditional] ceramic coating.
I don't know of a company that's comparable to Lodge, but that makes oiled/waxed outerwear.
Barbour traditionally made "oil coats" for fishermen. Then later waxed cotton jackets for farmers in the UK. They last for generations, you can rewax and repair them.
Belstaff made waxed motorcycle wear.
Both do amazingly high quality, if expensive, modern waxed and oiled cotton or canvas jackets and clothing.
Unless you count the workers in the foundry that is making them.
Needless to say, don't do that and cast iron presents no risks.
At the end of the day, a really silly reason to swear off cast iron.
Consumerism really did kill "us" for "me" didn't it.
The world will go on. We will find alternatives that don’t cause pain and suffering.
>Are these forever chemicals an actual big deal? Do we have any numbers on how many people or animals they injure or kill every year?
One study estimates about 30,000 to 120,000 people killed in America per year, with many more in the rest of the word. The EPA thinks reducing PFAS exposure now could save thousands of human lives per year and prevent tens of thousands of cases of human illnesses.
>How about projections into the future?
We really don't know. However, the numbers seem to have gone down significantly in recent years, perhaps due to a change in which PFAS people are exposed to.
>What kind of benefit do they allow manufacturers?
Calling PFAS miracle chemicals would be an understatement. Short chain PFAS (the dangerous kind) enable us to make PTFE, which makes surfaces almost friction-less, is compatible with almost every chemical, is largely bio-compatible, and lets water vapor through while keeping out liquid water (useful for things like waterproof jackets which don't trap sweat). They have a wide variety of other applications as well.
https://www.amazon.com/stores/phade/page/7B9D4729-8EDF-4FAE-...
6,000 regular sized straws for $55, so about a penny each.
https://www.amazon.com/phade-Eco-Friendly-Sustainable-Biodeg...
Perhaps limited liability should not apply to negligent harm caused by the entity to non-involved people. investors, officers and directors should be fully personally liable for the harms.
https://www.verywellhealth.com/cleaning-pfas-from-water-6500...
If we declare the situation hopeless then nothing will change.
Because it's a useful political slogan for the anti-PFAS advocates.
How are small towns supposed to pay for these treatment processes? How are individual home owners, since in many areas everyone is on a well?
What are all the marine critters (and everything that eats them, and everything that eats those critters, etc.) supposed to do?
All so McDonalds can make a Big Mack container that doesn't get soggy?
It's making us all sick. Slowly but surely.
If you want people not to accept it so we don't pollute our environment, just prevent the pollution directly. Also, I may not buy things with PFAS but there are millions of situation where PFAS could jeopardize my health (e.g food containers at restaurants, schools, hospitals… neighboring factory producing PFAS, etc).
The organization in the article is proposing banning production of the entire family of chemicals (~ 12,000 of them) instead of doing it one at a time.
3M reaches $10.3B settlement over PFAS contamination of water systems - https://news.ycombinator.com/item?id=36660751 - July 2023 (333 comments)
USGS estimates at least 45% of U.S. tap water contain forever chemicals - https://news.ycombinator.com/item?id=36617822 - July 2023 (169 comments)
Nearly half of the tap water in the US is contaminated with ‘forever chemicals,’ - https://news.ycombinator.com/item?id=36616841 - July 2023 (174 comments)
Water heavily polluted with PFAS in 15 km radius around Dordrecht chemical plant - https://news.ycombinator.com/item?id=36520610 - June 2023 (44 comments)
Show HN: PFAS.report – Measure the forever chemicals in your blood via Quest - https://news.ycombinator.com/item?id=36509752 - June 2023 (150 comments)
Eating microwave popcorn increases the level of PFAS in body (2022) - https://news.ycombinator.com/item?id=36440911 - June 2023 (414 comments)
3M heads to trial in ‘existential’ $143B forever-chemicals litigation - https://news.ycombinator.com/item?id=36259163 - June 2023 (250 comments)
Three companies agree to pay $1B to settle 'forever chemical' claims - https://news.ycombinator.com/item?id=36196884 - June 2023 (75 comments)
Many soft contact lenses in US made up of PFAS, research suggests - https://news.ycombinator.com/item?id=35955706 - May 2023 (109 comments)
America’s first high-volume ‘PFAS Annihilator’ is up and running in W. Michigan - https://news.ycombinator.com/item?id=35821128 - May 2023 (168 comments)
Engineers develop water filtration that removes “forever chemicals” - https://news.ycombinator.com/item?id=35764476 - April 2023 (226 comments)
Compostable fast-food packaging can emit volatile PFAS - https://news.ycombinator.com/item?id=35411919 - April 2023 (155 comments)
PFAS ban affects most refrigerant blends - https://news.ycombinator.com/item?id=34997937 - March 2023 (100 comments)
PFAS can suppress white blood cells’ ability to destroy invaders - https://news.ycombinator.com/item?id=34909058 - Feb 2023 (207 comments)
Magnetic method to clean PFAS contaminated water - https://news.ycombinator.com/item?id=34487079 - Jan 2023 (181 comments)
PFAS found at high levels in freshwater fish - https://news.ycombinator.com/item?id=34411713 - Jan 2023 (41 comments)
3M to end 'forever chemicals' output - https://news.ycombinator.com/item?id=34076685 - Dec 2022 (413 comments)
Pollution cleanup method destroys toxic “forever chemicals” - https://news.ycombinator.com/item?id=34047047 - Dec 2022 (80 comments)
Possible breakthrough to destroy PFAS using sodium hydroxide - https://news.ycombinator.com/item?id=32517444 - Aug 2022 (33 comments)
Simple mix of soap and solvent could help destroy ‘forever chemicals’ - https://news.ycombinator.com/item?id=32515511 - Aug 2022 (233 comments)
It’s raining PFAS: rainwater is unsafe to drink even in Antarctica and Tibet - https://news.ycombinator.com/item?id=32451024 - Aug 2022 (433 comments)
Study finds link between 'forever chemicals' in cookware and liver cancer - https://news.ycombinator.com/item?id=32438368 - Aug 2022 (394 comments)
Rainwater everywhere on Earth unsafe to drink due to ‘forever chemicals’ - https://news.ycombinator.com/item?id=32365736 - Aug 2022 (72 comments)
US water contains more ‘forever chemicals’ than EPA tests show - https://news.ycombinator.com/item?id=32004036 - July 2022 (21 comments)
3M’s PFAS Crisis Has Come to Europe - https://news.ycombinator.com/item?id=31809445 - June 2022 (94 comments)
Regular blood donations can reduce “forever chemicals” in the bloodstream: study - https://news.ycombinator.com/item?id=31123477 - April 2022 (204 comments)
PFAS Contamination in the U.S - https://news.ycombinator.com/item?id=28744886 - Oct 2021 (44 comments)
Toxic ‘forever chemicals’ contaminate indoor air at worrying levels - https://news.ycombinator.com/item?id=28367524 - Aug 2021 (144 comments)
Study finds alarming levels of ‘forever chemicals’ in US mothers’ breast milk - https://news.ycombinator.com/item?id=27139371 - May 2021 (107 comments)
Forever chemicals are widespread in U.S. drinking water - https://news.ycombinator.com/item?id=25887385 - Jan 2021 (258 comments)
Chemicals called PFAS and PFOS are in the blood of virtually every person - https://news.ycombinator.com/item?id=25557113 - Dec 2020 (226 comments)
PFAS “forever” chemicals found in hundreds more everyday products - https://news.ycombinator.com/item?id=25288978 - Dec 2020 (25 comments)
U.S. drinking water widely contaminated with 'forever chemicals': report - https://news.ycombinator.com/item?id=22116696 - Jan 2020 (391 comments)
Toxic ‘Forever Chemicals’ in Drinking Water Leave Military Families Reeling - https://news.ycombinator.com/item?id=19233284 - Feb 2019 (110 comments)
Scientists cut the tolerable intake of PFAs by 99.9% - https://news.ycombinator.com/item?id=19070754 - Feb 2019 (112 comments)
3M Knew About the Dangers of PFOA and PFOS Decades Ago, Internal Documents Show - https://news.ycombinator.com/item?id=17680589 - Aug 2018 (151 comments)
Troubling chemicals found in wide range of fast-food wrappers - https://news.ycombinator.com/item?id=13541466 - Feb 2017 (69 comments)
Google neutered their normal search engine, so in order to search by date I went to Google Scholar and I have found no use of such term well into the 2000s.
It looks like a journalistic invention, does anyone have am origin story pointing to a scholarly source?
Disregarding any nomenclature, in just focusing on the terminology in isolation, water could be considered a forever chemical. This is an example of why use of the term "forever chemical" comes off as a scare tactic or disingenuous.
Of course, for dying media institutions, PFAS can't just be a pollutant. It has to be literally forever!
EDIT: Way to go missing the entire point, all of you.
For a big chunk of the industrial age we've operated on the assumption that the global environment is big enough and capable enough to just eat or neutralize just about anything we dump into it. I think there is utility in defining a category of human-produced things that we have been able to determine the global environment can't eat or neutralize, and also that cause harm when people are exposed to them.
You could give this category a lot of potential names, but "forever chemicals" conveys the idea pretty effectively IMO.
https://en.wikipedia.org/wiki/Persistent_organic_pollutant
into google, gets you this link:
https://en.wikipedia.org/wiki/Per-_and_polyfluoroalkyl_subst...
"forever chemical" in either Google or DDG gives a lot of good links explaining what they are.
we'll never get rid of nuclear weapons
ergo, we'll never get rid of PFAS
It sounds at least like they're not going the terrible US route of allowing substances until proven toxic.
Perhaps we've hit enough technological development that any new chemical actually needs to have approval before it can be mass produced (of course giving labs freedom to experiment in developing new materials).