Who are you hosting on?
You can do everything right but are being judged by the history of your IP address with it's neighbours in the same AS block.
To what?
Switching ISPs is what got me into this mess in the first place. Also, I really like Linode but for this one issue.
If you want to use Linode for your CPU time and disk, probably there are providers for outbound SMTP that you pay a small amount for to use as a smarthost.