As for the "mathematically better tuned" comment, I've always disliked the arguments that one sex is better suited for anything, especially when talking about the brain. I think socialization has a lot more to do with brain development then sex, and since we've got hundreds of years of gender roles to overcome before we find out for sure, I think we're better off judging individuals, rather then genders.
As for why there aren't more women in startups, or women geeks for that matter, I return to socialization. Bill Gates made it cool to be a nerd for guys, we still don't have a female in that category. A largely successful role model that makes it ok for women to not be entirerly obsessed with their appearence. Maybe when I get my own start up...