For example, say you have a form. If you built it thinking online first you'll probably have some pessimistic UI which shows a spinner and waits for the server to respond with ok/error. You can't simply think, okay since we're offline, more latency -> show spinner for longer. You have to re-architect things so that the UI is optimistic, commits to a local database and that local database is synced up to the server when you come online.
In my experience optimistic UI is way more complex to build. Many times the complexity is worth it though.