The MiG-25 "Foxbat" is a famous example. To succeed in it's role as an high-speed interceptor it should have been made from titanium. But it's a very expensive and difficult metal to work with, so temperature critical parts were instead made from stainless steel. In the west there were lots of jokes about it rusting in the rain and the use of vacuum tubes, but tubes allowed it to have a very powerful radar. Plus that's what they had to work with (the Soviets having great difficulties making high-current semiconductors).
There was single significant defection before the introduction of the "teen" fighters, codenamed HAVE DOUGHNUT, and even it was not actually Soviet (an Iraqi pilot defected to Israel). All the other defections (which there were several) happened using old/non-fighter aircraft (iirc there were several MiG-15/17/19 which were essentially Korean War era designs), or happened after the teens were designed.
The alternative scenario, where the Mig-25 really was generations ahead, plays out in the movie Firefox from 1982 where the US is so far behind they have to steal a Soviet Mig-31 superplane. Good for laugh today, but once upon a time…
The rumor I heard is Soviet intelligence infiltrated American industry and stole what they thought were plans for America’s next generation air superiority fighter. What they’d obtained were the plans for Plymouth’s Roadrunner Superbird, thus the Mig-25’s uncanny resemblance. Proof: https://robbreport.com/motors/cars/1970-plymouth-superbird-a...
The Mig-25 seems like a good example of a Soviet aircraft considered better than its US contemporaries, at the time. Misunderstanding and misinformation let the US to think they were far, far behind the Soviet Union. Viktor Belenko cleared that up! It was a plane good at just one thing, with downsides that would never let it through a (non-CIA-directed) US procurement process. On the plus side, competition, fear, and rivalry, drove the US to some amazing research, engineering, and innovation.
As a child at a local military airshow, the F-15 was awesome, dangerously beautiful. Shamed even the X-wings and Tie fighters I'd just seen on the big screen. Many years later, I had a similar feeling watching an Su-27 at Farnborough; Sukhoi captured some aesthetic that Mikoyan-Gurevich never seemed to get right, and did it better than any western contemporary.