I'm sure that others can comment on that, but in my experience PL/pgSQL is the killer feature that's hard to beat in PostgreSQL, for those cases where you want to store some amount of logic in the database itself (MySQL stored procedures feel a bit more limited). That said, it's not even the only procedural language that is available: https://www.postgresql.org/docs/current/xplang.html
In addition, working with JSON in PostgreSQL can be pretty nice for niche use cases, as is using PostGIS for geospatial data, in addition to some of the REST (e.g. PostgREST) or GraphQL (e.g. PostGraphile) projects, if you want to interact with the database as something that exposes web endpoints to let you retrieve and manipulate data directly, as opposed to just SQL communication with some back end.
That's not to say that MySQL or MariaDB don't have their own great offerings, but it's clear that PostgreSQL has gotten a lot of love in regards to people developing various integrations and extensions. That said, usually not needing the equivalent of PgBouncer out of the box is nice and personally MySQL Workbench feels better than pgAdmin due to the advanced ER functionality (forwards/backwards engineering and schema synchronization, so that you can create versioned DB migrations more easily if you write them in plain SQL).
Edit: as for some crowd sourced data, a quick search turned up this from a few years ago: https://learnsql.com/blog/companies-that-use-postgresql-in-b...
But then again, all of the mentioned RDBMSes have proven themselves as viable for a variety of projects.