Do both.
Getting your hands dirty is the best way to understand how something works. Think about all the useless SE and PL work that gets done by folks who never programmed for a living, and how often faculty members in those fields with 10 yoe in industry spend their first few years back in academia just slamming ball after ball way out of the park.
More importantly, $500K gross is $300K net. Times 5 is $1.5, or time 10 is $3M. That's pretty good "fuck you" money. On top which some industry street cred allows new faculty to opt out of a lot of the ridiculous BS that happens in academia. Seen this time and again.
I think the easiest and best path for a fresh NLP phd grad can do right now is find the highest paying industry position, stick it out 5-10 years, then return as a profess of practice and tear it up pre-tenure (or just say f u to the tenure track because who needs tenure when you've got a flush brokerage account?)