You are welcome to use CAA accounturi without DNSSEC and it will be effective.
Your zone may be vulnerable to an active man-in-the-middle DNS attack (which is hard to pull off), but it will still be protected against somebody figuring out how to upload an /.well-known/acme-challenge/ file on your domain and issue an unauthorized certificate from a foreign ACME account. This attack is much easier - I did it against a popular mail provider a few years ago.