Interesting framework. Perhaps one of the difficulties is that decision reversibility tends to lie on a spectrum between "reversible" and "irreversible", and sometimes it's hard to even know where on that spectrum it lies. Thus you end up having to figure out if a decision is "reversible", maybe even first needing to develop a decision framework in which to make such a determination. I think all of the truly difficult decisions I've made in work and life have been in this category.
Still, I appreciate this concept and I think it's better to have the mental model than not.