80% isn't amazing, it's not ideal for an electric car, but it's not terrible either. IMO, to switch to 100% renewables, we're going to need grid-scale batteries, but it might also help if we had a mechanism to achieve seasonal energy storage.
I know hydrogen is hard to store, so I think it would be best if we could somehow use electricity to produce ethanol directly from CO2 and water (is that feasible with reasonable efficiency?). But just imagine if we could, in the summer, we could turn excess solar power into ethanol and stockpile it for the winter. We could also use that fuel to power jet airplanes and cargo ships without using any fossil fuels.